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What is 3 3 4 4 '- Biphenyltetracarboxylic dianhydride Bpda?

Author: Helen

Feb. 08, 2023

227 0 0

Tags: Chemicals

Biphenyltetracarboxylic dianhydride (BpDA) is an organic compound with the chemical formula C12H4O6. It is a white crystalline solid with a melting point of about 165°C. BpDA is used as a monomer in the synthesis of a wide range of polymers, including polyimides, which are known for their high temperature resistance and mechanical strength.

 

Polyimides are used in a variety of industrial applications, such as aerospace and electronic components, due to their excellent thermal stability and mechanical properties. The use of BpDA in the synthesis of polyimides has been well-studied, and it is a well-established precursor for the preparation of high-performance polymer materials.

 S-BPDA

In terms of synthesis, BpDA is typically synthesized by the reaction of two equivalents of biphenyl-4,4'-dicarboxylic acid with a dehydrating agent, such as phosphorus pentoxide. The reaction takes place in an organic solvent, such as dichloromethane, and the product is isolated by filtration and washed with water.

 

In terms of its structure, BpDA has a symmetrical, planar arrangement of atoms, with four carboxylic acid groups and four phenyl groups. The carboxylic acid groups are highly polar, while the phenyl groups are non-polar, which gives BpDA unique physical and chemical properties.

 

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BpDA is highly reactive, and can easily undergo reaction with amines, alcohols, and other active hydrogen-containing compounds. This reactivity is due to the presence of the highly polar carboxylic acid groups, which can form hydrogen bonds with other polar species.

 

In terms of applications, BpDA is used as a monomer in the synthesis of a wide range of polymers, including polyimides, polyamides, and polyamidoamine (PAA) dendrimers. Polyimides prepared from BpDA are known for their high temperature resistance, mechanical strength, and electrical insulation properties, making them useful in a variety of industrial applications, including aerospace and electronics.

 S-BPDA

In addition, BpDA is also used as a crosslinking agent for the preparation of epoxy resins, which are used in a wide range of applications, including adhesives, coatings, and composites. The crosslinking reaction between BpDA and epoxy resins is facilitated by the presence of the highly polar carboxylic acid groups, which can form hydrogen bonds with the epoxy resin.

 

In conclusion, Biphenyltetracarboxylic dianhydride (BpDA) is a versatile organic compound that is widely used as a monomer in the synthesis of a wide range of high-performance polymer materials, including polyimides, polyamides, and PAA dendrimers. Its unique physical and chemical properties, including high reactivity and thermal stability, make it useful in a variety of industrial applications.

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